Coexisting Clinpyroxene/Spinel and Amphibole/Spinel Symplectites in Metatroctolites from the Buck Creek Ultramafic Body, North Carolina Blue Ridge, USA

<p> <p id="x-x-x-p-1"> Buck Creek metatroctolites preserve evidence of three stages in the geologic history of the region: a relict igneous stage; a high-pressure, granulite-facies metamorphic stage; and a hydrous alteration stage. During high-pressure granulite-facies metamorphism, adjacent olivine and plagioclase reacted to produce complex coronitic textures. Relict olivine is surrounded by radial, columnar orthopyroxene, and plagioclase is rimmed by fine-grained symplectite composed of separate grains of clinopyroxene/spinel, tschermakitic amphibole/spinel symplectite and minor clinopyroxene/sapphirine symplectite. Examination of textural relationships in back-scattered electron images and X-ray element maps of the symplectites demonstrates that amphibole/spinel and clinopyroxene/spinel symplectites grew simultaneously at high temperature to replace plagioclase in these rocks. Clinopyroxene/sapphirine symplectite grew in the latest stages of plagioclase replacement in some samples. <p id="x-x-x-p-2"> A successful model for the main corona-forming reaction in sample BC7, 1.00 Pl + 1.72 Ol + 0.17 H ₂ O = 0.59 Di + 0.17 Amp + 0.68 Spl + 0.79 Opx, results only if amphibole is included. The model predicts relative volumes of product clinopyroxene, amphibole and spinel that are generally consistent with the proportions in imaged symplectites. Proportions of clinopyroxene-and amphibole-hosted symplectite appear to have been governed by local mass-balance of Na and Al in plagioclase and/or availability of H ₂ O. The most successful model for formation of the inner clinopyroxene/sapphirine corona, 1.00 Pl + 1.47 Ol + 0.17 H ₂ O = 0.59 Di + 0.17 Amp + 0.30 Spr (10 ox.) + 0.57 Opx, also includes amphibole, which is present in association with clinopyroxene/sapphirine symplectite. Sufficient H ₂ O for formation of symplectic amphibole must have been present in the intergranular fluid of relict igneous troctolites or have infiltrated during metamorphism at high <em> P-T </em> conditions. </p> </p></p>