TY - JOUR
T1 - Fumarolic Activity of Avachinsky and Koryaksky Volcanoes, Kamchatka, from 1993 to 1994
AU - Taran, Yuri A.
AU - Connor, Charles B.
AU - Shapar, Vyacheslav N.
AU - Ovsyannikov, Alexandre A.
AU - Bilichenko, Arthur A.
PY - 1997/4/1
Y1 - 1997/4/1
N2 - Volcanic gas and condensate samples were collected in 1993–1994 from fumaroles of Koryaksky and Avachinsky, basaltic andesite volcanoes on the Kamchatka Peninsula near Petropavlovsk–Kamchatsky. The highest-temperature fumarolic discharges, 220  °C at Koryaksky and 473  °C at Avachinsky, are water-rich (940–985 mmol/mol of H2O) and have chemical and isotopic characteristics typical of Kamchatka–Kurile, high- and medium-temperature volcanic gases. The temperature and chemical and water isotopic compositions of the Koryaksky gases have not changed during the past 11 years. They represent an approximate 2 : 1 mixture of magmatic and meteoric end members. Low-temperature, near-boiling-point discharges of Avachinsky Volcano are water poor (≈880 mmol/mol); Their compositions have not changed since the 1991 eruption, and are suggested to be derived from partially condensed magmatic gases at shallow depth. Based on a simple model involving mixing and single-step steam separation, low water and high CO2 contents, as well as the observed Cl concentration and water isotopic composition in low-temperature discharges, are the result of near-surface boiling of a brine composed of the almost pure condensed magmatic gas. High methane content in low-temperature Avachinsky gases and the 220  °C Koryaksky fumarole, low C isotopic ratio in CO2 at Koryaksky (–11.8‰), and water isotope data suggest that the "meteoric" end member contains considerable amounts of the regional methane-rich thermal water discovered in the vicinity of both volcanoes.
AB - Volcanic gas and condensate samples were collected in 1993–1994 from fumaroles of Koryaksky and Avachinsky, basaltic andesite volcanoes on the Kamchatka Peninsula near Petropavlovsk–Kamchatsky. The highest-temperature fumarolic discharges, 220  °C at Koryaksky and 473  °C at Avachinsky, are water-rich (940–985 mmol/mol of H2O) and have chemical and isotopic characteristics typical of Kamchatka–Kurile, high- and medium-temperature volcanic gases. The temperature and chemical and water isotopic compositions of the Koryaksky gases have not changed during the past 11 years. They represent an approximate 2 : 1 mixture of magmatic and meteoric end members. Low-temperature, near-boiling-point discharges of Avachinsky Volcano are water poor (≈880 mmol/mol); Their compositions have not changed since the 1991 eruption, and are suggested to be derived from partially condensed magmatic gases at shallow depth. Based on a simple model involving mixing and single-step steam separation, low water and high CO2 contents, as well as the observed Cl concentration and water isotopic composition in low-temperature discharges, are the result of near-surface boiling of a brine composed of the almost pure condensed magmatic gas. High methane content in low-temperature Avachinsky gases and the 220  °C Koryaksky fumarole, low C isotopic ratio in CO2 at Koryaksky (–11.8‰), and water isotope data suggest that the "meteoric" end member contains considerable amounts of the regional methane-rich thermal water discovered in the vicinity of both volcanoes.
KW - Key words Volcanic gases
KW - Vapor-liquid separation
KW - Avachinsky and Koryaksky volcanoes
KW - Kamchatka
UR - https://digitalcommons.usf.edu/geo_facpub/1662
UR - https://doi.org/10.1007/s004450050152
U2 - 10.1007/s004450050152
DO - 10.1007/s004450050152
M3 - Article
VL - 58
JO - Bulletin of Volcanology
JF - Bulletin of Volcanology
ER -