Lead Chloride Complexation Using Ultraviolet Molar Absorptivity Characteristics

Robert H. Byrne; Richard W. Young; William L. Miller

doi:10.1007/BF00645013

Lead Chloride Complexation Using Ultraviolet Molar Absorptivity Characteristics

Robert H. Byrne, Richard W. Young, William L. Miller

College of Marine Science

Research output: Contribution to journal › Article › peer-review

Abstract

The molar absorptivities of Pb ²⁺ , PbCl ⁺ , PbCl ₂ , and PbCl ⁻ ₃ were obtained between 210 and 300 nm. Molar absorptivity data were used to determine lead speciation directly from Pb(II) absorbance characteristics in a variety of media including natural seawater. The absorbance characteristics of lead in a particular chloride medium reveal the lead chloride formation constants appropriate to that medium. Our analyses indicate that lead chloride formation constants are significantly smaller in MgCl ₂ media than in HCl at constant ionic strength.

Original language	American English
Journal	Journal of Solution Chemistry
Volume	10
DOIs	https://doi.org/10.1007/BF00645013
State	Published - Jan 1 1981

Keywords

Lead chloride
molar absorptivity
complexation
medium dependence
ultraviolet
spectroscopic

Disciplines

Life Sciences

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10.1007/BF00645013License: CC BY

https://doi.org/10.1007/BF00645013

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title = "Lead Chloride Complexation Using Ultraviolet Molar Absorptivity Characteristics",

abstract = " The molar absorptivities of Pb 2+ , PbCl + , PbCl 2 , and PbCl − 3 were obtained between 210 and 300 nm. Molar absorptivity data were used to determine lead speciation directly from Pb(II) absorbance characteristics in a variety of media including natural seawater. The absorbance characteristics of lead in a particular chloride medium reveal the lead chloride formation constants appropriate to that medium. Our analyses indicate that lead chloride formation constants are significantly smaller in MgCl 2 media than in HCl at constant ionic strength.",

keywords = "Lead chloride, molar absorptivity, complexation, medium dependence, ultraviolet, spectroscopic",

author = "Byrne, {Robert H.} and Young, {Richard W.} and Miller, {William L.}",

year = "1981",

month = jan,

day = "1",

doi = "10.1007/BF00645013",

language = "American English",

volume = "10",

journal = "Journal of Solution Chemistry",

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TY - JOUR

T1 - Lead Chloride Complexation Using Ultraviolet Molar Absorptivity Characteristics

AU - Byrne, Robert H.

AU - Young, Richard W.

AU - Miller, William L.

PY - 1981/1/1

Y1 - 1981/1/1

N2 - The molar absorptivities of Pb 2+ , PbCl + , PbCl 2 , and PbCl − 3 were obtained between 210 and 300 nm. Molar absorptivity data were used to determine lead speciation directly from Pb(II) absorbance characteristics in a variety of media including natural seawater. The absorbance characteristics of lead in a particular chloride medium reveal the lead chloride formation constants appropriate to that medium. Our analyses indicate that lead chloride formation constants are significantly smaller in MgCl 2 media than in HCl at constant ionic strength.

AB - The molar absorptivities of Pb 2+ , PbCl + , PbCl 2 , and PbCl − 3 were obtained between 210 and 300 nm. Molar absorptivity data were used to determine lead speciation directly from Pb(II) absorbance characteristics in a variety of media including natural seawater. The absorbance characteristics of lead in a particular chloride medium reveal the lead chloride formation constants appropriate to that medium. Our analyses indicate that lead chloride formation constants are significantly smaller in MgCl 2 media than in HCl at constant ionic strength.

KW - Lead chloride

KW - molar absorptivity

KW - complexation

KW - medium dependence

KW - ultraviolet

KW - spectroscopic

UR - https://digitalcommons.usf.edu/msc_facpub/1664

UR - https://doi.org/10.1007/BF00645013

U2 - 10.1007/BF00645013

DO - 10.1007/BF00645013

M3 - Article

VL - 10

JO - Journal of Solution Chemistry

JF - Journal of Solution Chemistry

ER -

Lead Chloride Complexation Using Ultraviolet Molar Absorptivity Characteristics

Abstract

Keywords

Disciplines

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