Mixed Halide Complexes of Lead. A Comparison with Theoretical Predictions

Robert H. Byrne; Richard W. Young

doi:10.1007/BF01036380

Mixed Halide Complexes of Lead. A Comparison with Theoretical Predictions

Robert H. Byrne, Richard W. Young

College of Marine Science

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Abstract

Experimentally and theoretically derived formation constants of mixed lead halide complexes are compared at 25.0°C and one molar ionic strength. The formation constant of PbBrCl, β ₁₁ =79±10, is somewhat larger than the theoretical results, β ₁₁ =55, predicted using the formation constants of PbBr ₂ and PbCl ₂ . The molar absorptivity of PbBrCl was observed to be intermediate in character between the molar absorptivities of PbBr ₂ and PbCl ₂ . Determinations of the formation constants of PbBr ₂ Cl ⁻ and PbBrCl ₂ ⁻ are in reasonable agreement with the predictions based on the formation constants of PbBr ₃ ⁻ and PbCl ₃ ⁻ . Mixed ligand species dominated the complexation scheme of Pb(II) in our test media.

Original language	American English
Journal	Journal of Solution Chemistry
Volume	11
DOIs	https://doi.org/10.1007/BF01036380
State	Published - Jan 1 1982

Keywords

Lead
lead bromide
lead chloride
mixed ligand
complexation
spectroscopic

Disciplines

Life Sciences

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https://doi.org/10.1007/BF01036380

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title = "Mixed Halide Complexes of Lead. A Comparison with Theoretical Predictions",

abstract = " Experimentally and theoretically derived formation constants of mixed lead halide complexes are compared at 25.0°C and one molar ionic strength. The formation constant of PbBrCl, β 11 =79±10, is somewhat larger than the theoretical results, β 11 =55, predicted using the formation constants of PbBr 2 and PbCl 2 . The molar absorptivity of PbBrCl was observed to be intermediate in character between the molar absorptivities of PbBr 2 and PbCl 2 . Determinations of the formation constants of PbBr 2 Cl − and PbBrCl 2 − are in reasonable agreement with the predictions based on the formation constants of PbBr 3 − and PbCl 3 − . Mixed ligand species dominated the complexation scheme of Pb(II) in our test media.",

keywords = "Lead, lead bromide, lead chloride, mixed ligand, complexation, spectroscopic",

author = "Byrne, {Robert H.} and Young, {Richard W.}",

year = "1982",

month = jan,

day = "1",

doi = "10.1007/BF01036380",

language = "American English",

volume = "11",

journal = "Journal of Solution Chemistry",

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TY - JOUR

T1 - Mixed Halide Complexes of Lead. A Comparison with Theoretical Predictions

AU - Byrne, Robert H.

AU - Young, Richard W.

PY - 1982/1/1

Y1 - 1982/1/1

N2 - Experimentally and theoretically derived formation constants of mixed lead halide complexes are compared at 25.0°C and one molar ionic strength. The formation constant of PbBrCl, β 11 =79±10, is somewhat larger than the theoretical results, β 11 =55, predicted using the formation constants of PbBr 2 and PbCl 2 . The molar absorptivity of PbBrCl was observed to be intermediate in character between the molar absorptivities of PbBr 2 and PbCl 2 . Determinations of the formation constants of PbBr 2 Cl − and PbBrCl 2 − are in reasonable agreement with the predictions based on the formation constants of PbBr 3 − and PbCl 3 − . Mixed ligand species dominated the complexation scheme of Pb(II) in our test media.

AB - Experimentally and theoretically derived formation constants of mixed lead halide complexes are compared at 25.0°C and one molar ionic strength. The formation constant of PbBrCl, β 11 =79±10, is somewhat larger than the theoretical results, β 11 =55, predicted using the formation constants of PbBr 2 and PbCl 2 . The molar absorptivity of PbBrCl was observed to be intermediate in character between the molar absorptivities of PbBr 2 and PbCl 2 . Determinations of the formation constants of PbBr 2 Cl − and PbBrCl 2 − are in reasonable agreement with the predictions based on the formation constants of PbBr 3 − and PbCl 3 − . Mixed ligand species dominated the complexation scheme of Pb(II) in our test media.

KW - Lead

KW - lead bromide

KW - lead chloride

KW - mixed ligand

KW - complexation

KW - spectroscopic

UR - https://digitalcommons.usf.edu/msc_facpub/1666

UR - https://doi.org/10.1007/BF01036380

U2 - 10.1007/BF01036380

DO - 10.1007/BF01036380

M3 - Article

VL - 11

JO - Journal of Solution Chemistry

JF - Journal of Solution Chemistry

ER -

Mixed Halide Complexes of Lead. A Comparison with Theoretical Predictions

Abstract

Keywords

Disciplines

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