Production of Potentially Prebiotic Condensed Phosphates by Phosphorus Redox Chemistry

Matthew A. Pasek, Terence P. Kee, David E. Bryant, Alexander A. Pavlov, Jonathan I. Lunine

Research output: Contribution to journalArticlepeer-review

Abstract

Bringing phosphorus to life : The prebiotic origin of key biomolecules such as RNA and ATP is contingent on a source of condensed phosphates, such as pyrophosphate and triphosphate. Condensed phosphates can be produced at high yields from the oxidation of H-phosphonate or H-phosphinate. Reactive phosphates were likely abundant on the early earth's surface, setting the stage for prebiotic chemistry that led to the evolution of life.

Original languageAmerican English
JournalAngewandte Chemie International Edition
Volume47
DOIs
StatePublished - Jan 1 2008
Externally publishedYes

Keywords

  • origins of life
  • phosphorus
  • phosphorylation
  • prebiotic chemistry
  • redox chemistry

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