Simulations of the Redistribution of Formaldehyde, Formic Acid, and Peroxides in the 10 July 1996 Stratospheric‐Tropospheric Experiment: Radiation, Aerosols, and Ozone Deep Convection Storm

M. C. Barth, S.-W. Kim, W. C. Skamarock, Amy L. Stuart, K. E. Pickering, L. E. Ott

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Abstract

<p> By using a three&hyphen;dimensional convective cloud model to simulate the 10 July 1996, Stratospheric&hyphen;Tropospheric Experiment: Radiation, Aerosols, and Ozone&hyphen;Deep Convection experiment storm, we investigate the fate of formaldehyde (CH <sub> 2 </sub> O), formic acid (HCOOH), hydrogen peroxide (H <sub> 2 </sub> O <sub> 2 </sub> ), and methyl hydrogen peroxide (CH <sub> 3 </sub> OOH) in an isolated thunderstorm. CH <sub> 2 </sub> O, H <sub> 2 </sub> O <sub> 2 </sub> , and CH <sub> 3 </sub> OOH are important HO <em> x </em> radical and ozone (O <sub> 3 </sub> ) precursors in the upper troposphere. Thus, determining their source strength to the upper troposphere is important for estimating O <sub> 3 </sub> production. The model simulates O <sub> 3 </sub> &hyphen;NO <sub> <em> x </em> </sub> &hyphen;CH <sub> 4 </sub> chemistry (no nonmethane hydrocarbon chemistry) which is affected by the cloud microphysics and production of NO <em> x </em> by lightning. The retention of the soluble species within ice, snow, and hail during drop freezing results in less transport of the species to the upper troposphere than when the species is degassed during drop&hyphen;freezing processes. Aqueous&hyphen;phase chemistry is found to be inadequate in producing sufficient quantities of HCOOH so that HCOOH could serve as a reliable indicator of cloud&hyphen;processed air. The production of nitrogen oxides by lightning has little to no effect on convective outflow mixing ratios of CH <sub> 2 </sub> O, H <sub> 2 </sub> O <sub> 2 </sub> , and CH <sub> 3 </sub> OOH within 100 km of the convective cores. Thus, it is unlikely that lightning affects concentrations of HO <sub> <em> x </em> </sub> precursors near active convection. Scavenging of CH <sub> 2 </sub> O and H <sub> 2 </sub> O <sub> 2 </sub> significantly affects their concentrations in the convective outflow, although H <sub> 2 </sub> O <sub> 2 </sub> mixing ratios were still similar to CH <sub> 3 </sub> OOH indicating that both peroxides can contribute equally to O <sub> 3 </sub> production downwind of convection.</p>
Original languageAmerican English
JournalJournal of Geophysical Research: Atmospheres
Volume112
DOIs
StatePublished - Jul 1 2007

Keywords

  • Clouds and chemistry
  • deep convection
  • HOx precursors

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